Neutral Evil are characters who act based on what benefits them. Sometimes they're on the side of the heroes and sometimes they're on the side of the villains. Most anti-heroes fit into this alignment.
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- Sadaso
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- Sarah Karrigan
- Sephiroth (Final Fantasy)
- Sephiroth (Kingdom Hearts)
- Sesshōmaru
- Shaiapouf
- Shang Tsung
- Shao Kahn
- Shatter
- Shinnok
- Shizuku
- Shockwave (Transformers Cinematic Universe)
- Silver Samurai
- Sird
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- Sombra
- Sorey (Fractured)
- Soundwave (Transformers Cinematic Universe)
- Spark Man
- Specter (Ape Escape)
- Specter Knight
- Starscream (G1)
- Starscream (Transformers Cinematic Universe)
- Stay Puft Marshmallow Man
- Strike (OK K.O.! Let's Be Heroes)
- Sundowner
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- Sylvanas Windrunner
- Syndrome
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